Butane-1,2,3,4-tetracarboxylic acid–1,10-phenanthroline–water (1/2/2)
نویسنده
چکیده
The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol-ecule, one half-mol-ecule of butane-1,2,3,4-tetra-carb-oxy-lic acid (H(4)BTC) and a water mol-ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter-molecular O-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.672 (2) and 3.708 (2) Å form an extensive three-dimensional network, which consolidates the crystal packing.
منابع مشابه
Synthesis, Topological Analysis and Properties of a Coordination Polymer with Butane-1,2,3,4-tetracarboxylato-bridged (Phenanthroline)cobalt(II) Units
A hydrothermal reaction of Co(Ac)2 · 4H2O, butane-1,2,3,4-tetracarboxylic acid (H4BTC), 1,10-phenanthroline (phen) and NaOH carried out at 160 ◦C yielded a new complex [Co2(H2O)2(phen)2(BTC)]. The complex has been characterized by single-crystal X-ray diffraction, IR spectroscopy, TG-DTA analyses, elemental analyses, powder X-ray diffraction, and magnetic measurements. The Co ions are linked by...
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